Opening and closing process of the Paleo-Tethys in Northern Thailand     

Hidetoshi HARA  Koji WAKITA  Jun-ichiro KURODA  Toshiyuki KURIHARA  Katsumi UENO  Yoshihito KAMATA  Ken-ichiro HISADA  Punya CHARUSIRI  Thasinee CHAROENTITIRAT  Pol CHAODUMRONG 《地球学报》2009,30(Z1):12-12

The Paleo-Tethys formed a large ocean basin that existed between Laurasia and Gondwana during Late Paleozoic to Early Mesozoic times. It opened in the Early Devonian by the rifting of Gondwanaland and closed at around latest Triassic time by the collision of the Cimmerian continent to Laurasia (Metcalfe, 1999). We reconstructed opening and closing process of the Paleo-Tethys in Northern Thailand.  相似文献   

Theoretical and experimental investigation of nickel isotopic fractionation in species relevant to modern and ancient oceans     

Toshiyuki Fujii  Frédéric Moynier  Minori Abe 《Geochimica et cosmochimica acta》2011,75(2):469-7643

Nickel plays a central role as an enzyme co-factor in the metabolism of methanogenic Archaea. Methanogens can fractionate Ni isotopes during assimilation, opening the possibility of using the stable isotopic composition of Ni as a biomarker. However, other sources of Ni isotopic variations need to be evaluated before one can establish Ni isotopes as an unambiguous tracer of methanogenesis in the rock record. Equilibrium exchange of Ni between the different species present in the ocean is a potential source of isotopic fractionation. Through controlled laboratory experiments and theoretical calculations, we quantify equilibrium Ni isotope fractionation between different species relevant to the modern and ancient ocean: Ni(H₂O)₆²⁺, Ni(H₂O)₁₈²⁺, NiOH(H₂O)₅⁺, Ni(OH)₂(H₂O)₄, NiCl(H₂O)₅⁺, cis-NiCl₂(H₂O)₄, trans-NiCl₂(H₂O)₄, NiHS(H₂O)₅⁺, Ni(HS)₂(H₂O)₄, NiSO₄(H₂O)₄, NiHCO₃(H₂O)₄⁺, NiCO₃(H₂O)₄, and organic ligands (crown ether and oxalic acid). The magnitude of ligand-controlled Ni isotopic fractionation, approximately 1.25‰/amu (2.5‰ for the ⁶⁰Ni/⁵⁸Ni ratio), is similar to that previously measured in cultures of methanogenic Archaea.  相似文献   

Ab initio calculations of the Fe(II) and Fe(III) isotopic effects in citrates,nicotianamine, and phytosiderophore,and new Fe isotopic measurements in higher plants     

Frédéric Moynier  Toshiyuki Fujii  Kun Wang  Julien Foriel 《Comptes Rendus Geoscience》2013,345(5-6):230-240

Iron is one of the most abundant transition metal in higher plants and variations in its isotopic compositions can be used to trace its utilization. In order to better understand the effect of plant-induced isotopic fractionation on the global Fe cycling, we have estimated by quantum chemical calculations the magnitude of the isotopic fractionation between different Fe species relevant to the transport and storage of Fe in higher plants: Fe(II)-citrate, Fe(III)-citrate, Fe(II)-nicotianamine, and Fe(III)-phytosiderophore. The ab initio calculations show firstly, that Fe(II)-nicotianamine is ～3‰ (⁵⁶Fe/⁵⁴Fe) isotopically lighter than Fe(III)-phytosiderophore; secondly, even in the absence of redox changes of Fe, change in the speciation alone can create up to ～1.5‰ isotopic fractionation. For example, Fe(III)-phytosiderophore is up to 1.5‰ heavier than Fe(III)-citrate₂ and Fe(II)-nicotianamine is up to 1‰ heavier than Fe(II)-citrate. In addition, in order to better understand the Fe isotopic fractionation between different plant components, we have analyzed the iron isotopic composition of different organs (roots, seeds, germinated seeds, leaves and stems) from six species of higher plants: the dicot lentil (Lens culinaris), and the graminaceous monocots Virginia wild rye (Elymus virginicus), Johnsongrass (Sorghum halepense), Kentucky bluegrass (Poa pratensis), river oat (Uniola latifolia), and Indian goosegrass (Eleusine indica). The calculations may explain that the roots of strategy-II plants (Fe(III)-phytosiderophore) are isotopically heavier (by about 1‰ for the δ⁵⁶Fe) than the upper parts of the plants (Fe transported as Fe(III)-citrate in the xylem or Fe(II)-nicotianamine in the phloem). In addition, we suggest that the isotopic variations observed between younger and older leaves could be explained by mixing of Fe received from the xylem and the phloem.  相似文献   

Nuclear field shift in natural environments     

Frédéric Moynier  Toshiyuki Fujii  Gregory A. Brennecka  Sune G. Nielsen 《Comptes Rendus Geoscience》2013,345(3):150-159

The nuclear field shift (NFS) is an isotope shift in atomic energy levels caused by a combination of differences in nuclear size and shape and electron densities at the nucleus. The effect of NFS in isotope fractionation was theoretically established by Bigeleisen in 1996 [Bigeleisen J. (1996) J. Am. Chem. Soc. 118:3676–3680] and has been analytically measured in laboratory chemical exchange reactions. More recently, some isotopic variations of heavy elements (Hg, Tl, U) measured in natural systems as well as isotopic anomalies measured for lower-mass elements in meteorites have been attributed to the NFS effect. These isotopic variations open up new and exciting fields of investigations in Earth sciences. In this paper, we review the different natural systems in which NFS has been proposed to be the origin of isotopic variations.  相似文献   

Radiolaria‐dated Lower Permian clastic‐rock sequence in the Fukuji area of the Hida‐gaien terrane,central Japan,and its inter‐terrane correlation across Southwest Japan     

Toshiyuki Kurihara  Masao Kametaka 《Island Arc》2008,17(4):531-545

The stratigraphy and radiolarian age of the Mizuyagadani Formation in the Fukuji area of the Hida‐gaien terrane, central Japan, represent those of Lower Permian clastic‐rock sequences of the Paleozoic non‐accretionary‐wedge terranes of Southwest Japan that formed in island arc–forearc/back‐arc basin settings. The Mizuyagadani Formation consists of calcareous clastic rocks, felsic tuff, tuffaceous sandstone, tuffaceous mudstone, sandstone, mudstone, conglomerate, and lenticular limestone. Two distinctive radiolarian faunas that are newly reported from the Lower Member correspond to the zonal faunas of the Pseudoalbaillella u‐forma morphotype I assemblage zone to the Pseudoalbaillella lomentaria range zone (Asselian to Sakmarian) and the Albaillella sinuata range zone (Kungurian). In spite of a previous interpretation that the Mizuyagadani Formation is of late Middle Permian age, it consists of Asselian to Kungurian tuffaceous clastic strata in its lower part and is conformably overlain by the Middle Permian Sorayama Formation. An inter‐terrane correlation of the Mizuyagadani Formation with Lower Permian tuffaceous clastic strata in the Kurosegawa terrane and the Nagato tectonic zone of Southwest Japan indicates the presence of an extensive Early Permian magmatic arc(s) that involved almost all of the Paleozoic non‐accretionary‐wedge terranes in Japan. These new biostratigraphic data provide the key to understanding the original relationships among highly disrupted Paleozoic terranes in Japan and northeast Asia.  相似文献   

Attenuation behaviour of tuffaceous sandstone and granite during microfracturing   总被引：1，自引：0，他引：1  

Angelika-M. Wulff  Toshiyuki Hashida  Kimio Watanabe  & Hideaki Takahashi 《Geophysical Journal International》1999,139(2):395-409

Laboratory measurements of ultrasonic wave propagation in tuffaceous sandstone (Kimachi, Japan) and granite (Iidate, Japan) were performed during increasing fracturing of the samples. The fracturing was achieved by unconfined uniaxial compression up to and beyond the point of macrofracture of the specimen using a constant low strain rate. The observed variation of wave velocity (up to 40 per cent) due to the development of micro- and macrofractures in the rock is interpreted by rock models relating velocity changes to damage and crack density. The calculated density of the newly formed cracks reaches higher values for the sandstone than for the granite. Using the estimated crack densities, the attenuation behaviour is interpreted in terms of different attenuation mechanisms; that is, friction and scattering. Rayleigh scattering as described by the model of Hudson (1981 ) may explain the attenuation qualitatively if the largest plausible crack dimensions are assumed in modelling.  相似文献   

Short term variability of Particle fluxes and its relation to variability in sea surface temperature and chlorophylla field detected by Ocean Color and Temperature Scanner (OCTS) off Sanriku, northwestern North Pacific in the spring of 1997     

Toshiro Saino  Shaoling Shang  Yoshihisa Mino  Koji Suzuki  Hideaki Nomura  Sei-ichi Saitoh  Hideo Miyake  Toshiyuki Masuzawa  Koh Harada 《Journal of Oceanography》1998,54(5):583-592

A sediment trap experiment was carried out in conjunction with an over flight of Ocean Color Temperature Scanner (OCTS) on board Advanced Earth Observing Satellite (ADEOS) at 40°N, 143°E off Sanriku in April to May 1997. Short term variability of particle fluxes was examined at depths of 450 m and 600 m from April 6 to May 1 with a sampling interval of two days, and at 450 m with one day interval from 2nd to 10th May. Daily averaged mass flux at 450 m and 600 m was 815 mg m⁻²d⁻¹ and 862 mg m⁻²d⁻¹, respectively. A sharp increase in mass flux was observed during the period from April 26 to April 29 with the highest mass flux of 8 g m⁻²d⁻¹. About 85% of the total mass flux for the entire duration (26 days) was collected within these 4 days. Trapped material during the peak flux period was mainly composed of diatoms dominated byThalassiosira spp. and resting spores ofChaetoceros spp. This suggested that the peak flux was the result of (a) diatom bloom(s) in the euphotic column. Current meter records at 420 m showed that on April 26 and 27, the period when the peak flux was observed, the southwestward current had diminished in strength and changed its direction northwestward. Low current speeds appeared to have enhanced trap efficiency to help form the peak flux. A time series of OCTS Intensive-LAC (Local Area Coverage: Region B) images from mid-March to early May was examined todetect phytoplankton bloom(s). In the March 26th Chl image, high concentration region was restricted to the southwest off Cape Erimo, but spread around the warm core ring (WCR) 93A by April 10. East of the WCR93A, high Chl concentration remained steady until May, but to the west of the WCR93A, Chl decreased rapidly before the 19th of April. From this observation we suspect that the peak flux observed at the end of April originated from a bloom, which ceased on the 17th or 18th of April, in the region north of 40°N and west of 143°E. Taking the current meter records into account, the source region for the trapped material is most likely around southwest of the Cape Erimo.  相似文献   

Seasonal Variation of Stratification in the Gulf of Thailand     

Tetsuo Yanagi  Suhendar I Sachoemar  Toshiyuki Takao  Shunji Fujiwara 《Journal of Oceanography》2001,57(4):461-470

Intensive hydrographic observations were carried out in the western part of the Gulf of Thailand and the east coastal sea of Peninsular Malaysia in September 1995 and April–May 1996. The characteristics of seasonal variation of oceanic condition in that area are discussed basis of an analysis of observed water temperature, salinity and density distributions in these cruises and NAGA cruises (Yanagi and Takao, 1998a). Stratification is most developed in March–May mainly due to large sea surface heating and weak sea surface wind, which weakened until September–October, vanishing in December–January. The horizontal distribution of bottom cold, saline and heavy water masses, which are found during the stratified season, is governed by the tidal mixing and the water depth. Water exchange between the Gulf of Thailand and the South China Sea becomes large in March–May due to a coupled effect of the intensified estuarine circulation and the Ekman transport by the southwest monsoon. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

The reversible effect of temperature on the chemical composition of interstitial water of marine sediment     

Toshiyuki Masuzawa  Satoru Kanamori  Yasushi Kitano 《Journal of Oceanography》1980,36(1):68-72

The reversibility of the temperature effect on the chemical composition of interstitial waters of three deep-sea sediment samples was examined between 2 and 25°C for Cl, Na, K, Mg, Ca, Si, B, Mn and alkalinity. When the temperature of sediment samples was returned from 25°C to the initial value of 2°C, most chemical species gave nearly their initial concentrations. However, for alkalinity and in one case for magnesium, it took another three to four hours to reach their initial concentrations.  相似文献   

Interannual variability and predictability of summertime significant wave heights in the western north pacific     

Wataru Sasaki  Hibiya Toshiyuki 《Journal of Oceanography》2007,63(2):203-213

We propose and validate a linear regression model which enables us to predict the summer (June–August) mean of the monthly 90th percentile of significant wave heights (H₉₀) in the western North Pacific (WNP). The most prevailing interannual variability of H⁹⁰ is identified by applying an Empirical Orthogonal Function analysis to H⁹⁰ obtained from the ERA-40 wave reanalysis as well as from the optimally interpolated TOPEX/Poseidon (OITP) wave data. It is found that the increase of H⁹⁰ is correlated with cyclonic circulation in the WNP which links with warm SST anomalies in the Niño-3.4 region. We adopt zonal wind anomaly averaged over the region 5°N–15°N, 130°E–160°E (U^10N) as a predictor of the first principal component (PC1) of H⁹⁰, since U^10N is closely correlated with the PC1 of H⁹⁰. It is revealed that regression models obtained from two different wave datasets are nearly identical. The predictability of the regression model is assessed in terms of the reduction of the root-mean-square (rms) errors between H⁹⁰ and the reconstructed data. The predictor is found to be successful in reducing the rms errors by up to 40% for the ERA-40 wave reanalysis and by up to 70% for the OITP wave data within the latitudinal band 10°N–25°N, though rms errors exceeding 0.3 m still remain, particularly in the East China Sea.  相似文献